My thinking is the brass keeps the chamber temp more stable.
As Jim stated, brass does not conduct heat like aluminum. Coefficient of thermal conduction (btu/hr-ft-*F) of aluminum is 104, when brass is 67. Nearly 1/2 like Jim said. But, aluminum dissipates heat quicker which makes up for some. All in all, brass -might- help achieve less temperature 'around the combustion chamber'. Hey Marty, How about a bimetal head, brass on the squish band , bowl still aluminum, send me a sample head and $300 and I'll make you one.
Seriously though, I'm surprised of Marty having expansion problems, 2024 aluminum is 12.9, and yellow brass is 11.3. I still say mod your engine and stay with aluminum.