The hardest part is making the plug! :blink:
I've made a few molds over the years and here's what I've settled on:
1. Prime and sand the plug smooth with 400 grit. Foam makes great plug material, coat with a thin layer of cloth and West Systems to seal. Make the base big and you'll thank yourself later on.
2. Wax with 3 coats of Partall #2, brush 1 coat of Partall Film #10 (PVA),
http://www.rexco-usa.com/part2.htm
3. Brush 2 coats of "vinyl ester tooling gelcoat", my supplier calls it G23X, it's made to take post cure heat.
4. Apply 2 coats of 6 oz cloth with "isophalic" or "tooling" resin, made for mold making.
5. Apply 2 coats of 18oz "tooling cloth", made to drape well over molds. I used that chopped strand "mat" for my first few and this cloth is much easier to work with and much stronger.
If you can't have the smell of fiberglass in the house you can use epoxy but it'll be expensive. I've used "cabosil" mixed with the resin to make a gelcoat.
Have fun!